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Integrated circuit
miniaturization continues to well below the half-micron level in the quest
for higher speed and greater efficiency. At such reduced dimensions, the
relatively high dielectric constant and resulting capacitance of
conventional interlayer dielectric materials works to limit signal speed,
create cross-talk and consume excessive power.
The search continues for
alternatives to SiO2 layers for many microelectronic device
applications. For lower than 0.25m
gap fill requirements, the search is now on for low dielectric constants
that can work well with metal deposition and planarization schemes. For
0.35m
gaps, fluorinated oxides,
such as the silicon oxyfluorides (SiOF), which can have a dielectric
constant as low as 3.2 (compared to about 3.9 for typical SiO2
films), provide the easiest way to accomplish this. The HDP-CVD deposited
SiOF has already been used to fill 0.35m,
and 0.25m
gaps, and is also a contender
even for the 0.18m
gaps. However, the HDP-CVD has proven very difficult to implement even for the 0.25m
gaps. Stability is the greatest concern for the HDP-CVD deposited SiOF
films.
For future ULSI, Semiconductor
Roadmap calls for dielectrics with k=2.5-3.0 for 0.18 mm devices and
2.0-2.5 at 0.15 mm or 0.13 mm. For various reasons oxide layers will
continue to be used with low-k dielectrics. For gaps of 0.25m,
0.18m,
0.13m,
0.10m
and lower, a variety of materials that can provide dielectric constants
between 2 and 3 are under development (e.g. fluorinated polymides,
non-polymide C-H polymers, fluoro-polymers, siloxane polymers and
parylenes, to name a few). All of these materials are just now beginning
to be fully characterized. Thus far, the biggest common concerns are
their relatively poor step coverage, low thermal conductivity, and
lack of stability.
Some of the concerns associated with
the above growth or deposition technologies of low dielectric constant
insulators for Si-based ULSI applications are:
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poor compatibility with multilevel
interconnection;
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deposition and post deposition
treatments (e.g. planarization) introduce stress and chemical and
particle contamination;
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relatively poor
thermal, UV, and plasma stability;
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high temperature;
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low deposition rate;
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relatively poor step coverage;
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high investment cost.
Hence, a selective RTWCG of SiOX
films for fully planarized multilevel interconnections, is attractive for
VLSI and ULSI device applications, by eliminating the CMP process.
SPECMAT,
Inc. has demonstrated the use of its revolutionary RTWCG
process to grow low dielectric constant (2<k<3) stable SiO-based
dielectric films capable of filling high aspect ratio nano-sized features.
We have also demonstrates that the SPECMAT proprietary RTWCG process has competitive merits compared to other dielectric
growth/deposition techniques for a variety of deep submicron IC’s
applications.
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